How To Make Pie Chart With Column Chart Detail

Data looks like this
bar-of-pie-excel-04.gif

Select as usual, Insert > choose this type of pie chart.
bar-of-pie-excel-01.gif
Excel will make arbitrary choice about which slice to give a detail breakout column. Select the breakout column and right click to format data
bar-of-pie-excel-02.gif
This bring up Format Data Series dialog box with multiple choices about how many and which slices to show in the break out column chart.
bar-of-pie-excel-03.gif
Explore.